Reactions of a Phosphinoimino-thiazoline-Based Metalloligand with Organic and Inorganic Electrophiles and Metal-Induced Ligand Rearrangements

Volume: 29, Issue: 24, Pages: 6660 - 6667
Published: Nov 24, 2010
Abstract
The reaction of the neutral Pt(II) bischelated complex cis-[Pt{Ph2PN···C···NCH2CH2S}2] ([Pt(2−H)2], 1; 2 = Ph2PNHC═NCH2CH2S, N-(diphenylphosphino)-thiazoline-2-amine) with the organic electrophile EtN═C═S yielded complex [Pt(2−H)(2−H·EtNCS)] (3) as a result of the nucleophilic attack of the coordinated 2-((diphenylphosphino)imino)thiazolidin-3-yl moiety on the heteroallene carbon atom and coordination of the sulfur atom to the metal. The...
Paper Details
Title
Reactions of a Phosphinoimino-thiazoline-Based Metalloligand with Organic and Inorganic Electrophiles and Metal-Induced Ligand Rearrangements
Published Date
Nov 24, 2010
Volume
29
Issue
24
Pages
6660 - 6667
Citation AnalysisPro
  • Scinapse’s Top 10 Citation Journals & Affiliations graph reveals the quality and authenticity of citations received by a paper.
  • Discover whether citations have been inflated due to self-citations, or if citations include institutional bias.