Review paper
A Survey of the Role of Noncovalent Sulfur Interactions in Drug Design
Abstract
Electron deficient, bivalent sulfur atoms have two areas of positive electrostatic potential, a consequence of the low-lying σ* orbitals of the C–S bond that are available for interaction with electron donors including oxygen and nitrogen atoms and, possibly, π-systems. Intramolecular interactions are by far the most common manifestation of this effect, which offers a means of modulating the conformational preferences of a molecule. Although a...
Paper Details
Title
A Survey of the Role of Noncovalent Sulfur Interactions in Drug Design
Published Date
Mar 3, 2015
Volume
58
Issue
11
Pages
4383 - 4438
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