Photomechanical Actuation of Ligand Geometry in Enantioselective Catalysis
Volume: 53, Issue: 52, Pages: 14508 - 14511
Published: Oct 30, 2014
Abstract
A catalyst that couples a photoswitch to the biaryl backbone of a chiral bis(phosphine) ligand, thus allowing photochemical manipulation of ligand geometry without perturbing the electronic structure is reported. The changes in catalyst activity and selectivity upon switching can be attributed to intramolecular mechanical forces, thus laying the foundation for a new class of catalysts whose selectivity can be varied smoothly and in situ over a...
Paper Details
Title
Photomechanical Actuation of Ligand Geometry in Enantioselective Catalysis
Published Date
Oct 30, 2014
Volume
53
Issue
52
Pages
14508 - 14511
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