Original paper
Synthesis and structures of monomeric group 14 triols and their reactivity
Abstract
The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and -germane. The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy. The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn–O–Si–O–Sn linkages in the...
Paper Details
Title
Synthesis and structures of monomeric group 14 triols and their reactivity
Published Date
Jun 1, 2014
Volume
92
Issue
6
Pages
542 - 548
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Notes
History