Original paper
Regenerable Antioxidants-Introduction of Chalcogen Substituents into Tocopherols
Abstract
To improve the radical‐trapping capacity of the natural antioxidants, alkylthio‐, alkylseleno‐, and alkyltelluro groups were introduced into all vacant aromatic positions in β‐, γ‐ and δ‐tocopherol. Reaction of the tocopherols with electrophilic chalcogen reagents generated by persulfate oxidation of dialkyl dichalcogenides provided convenient but low‐yielding access to many sulfur and selenium derivatives, but failed in the case of tellurium....
Paper Details
Title
Regenerable Antioxidants-Introduction of Chalcogen Substituents into Tocopherols
Published Date
Dec 11, 2014
Volume
21
Issue
6
Pages
2447 - 2457
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Notes
History