Two new coordination polymers employing 2,2′-bipyridine-3,3′,6,6′-tetracarboxylate as a ligand
Abstract
Two new coordination polymers employing 2,2′-bipyridine-3,3′,6,6′-tetracarboxylate (bptc) as a ligand are presented: [Mn2(H2O)5(bptc)]n (1) and [Cu2(H2O)2(bptc)]n·2nH2O (2). 1 is a 2D coordination polymer stabilized by Mn–O coordination bonds, where magnetic interactions are transmitted within carboxylate-bridged chains. 2 forms polymeric double chains. 1 and 2 are characterized by X-ray diffraction studies, IR spectra, elemental analysis and...
Paper Details
Title
Two new coordination polymers employing 2,2′-bipyridine-3,3′,6,6′-tetracarboxylate as a ligand
Published Date
Nov 1, 2013
Journal
Volume
408
Pages
193 - 198
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