Non-equilibrium cobalt(III) “click” capsules
Abstract
Cobalt(III) tetrahedral capsules have been prepared using an assembly-followed-by-oxidation protocol from a cobalt(II) precursor and a readily derivatizable pyridyl-triazole ligand system. Experiments designed to probe the constitutional dynamics show that these architectures are in a non-equilibrium state. A preliminary investigation into the host–guest chemistry of a water-soluble derivative shows it can bind and differentiate a range of...
Paper Details
Title
Non-equilibrium cobalt(III) “click” capsules
Published Date
Jan 1, 2015
Journal
Volume
6
Issue
1
Pages
756 - 760
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Notes
History