Thermal decomposition reaction and a comprehensive kinetic model of dimethyl ether

Volume: 40, Issue: 1, Pages: 1 - 18
Published: Jan 1, 2008
Abstract
The unimolecular decomposition reaction of dimethyl ether (DME) was studied theoretically using RRKM/master equation calculations. The calculated decomposition rate is significantly different from that utilized in prior work (Fischer et al., Int J Chem Kinet 2000, 32, 713–740; Curran et al., Int J Chem Kinet 2000, 32, 741–759). DME pyrolysis experiments were performed at 980 K in a variable-pressure flow reactor at a pressure of 10 atm, a...
Paper Details
Title
Thermal decomposition reaction and a comprehensive kinetic model of dimethyl ether
Published Date
Jan 1, 2008
Volume
40
Issue
1
Pages
1 - 18
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