Pentamethylcyclopentadienyl rhodium and iridium complexes containing oxinato ligands
Abstract
The neutral chloro complexes [(η5-C5Me5)M(η2-NC9H6O)Cl] as well as the cationic aqua complexes [(η5-C5Me5)M(η2-NC9H6O)(H2O)]+ (M = Rh, Ir) have been synthesized from the reaction of the dinuclear precursors [(η5-C5Me5)MCl2]2 and 8-hydroxyquinoline. The single crystal X-ray structure analysis of [(η5-C5Me5)Ir(η2-NC9H6O)Cl] reveals for these complexes a piano-stool arrangement with the aromatic ligand, the chelating oxinato ligand and the terminal...
Paper Details
Title
Pentamethylcyclopentadienyl rhodium and iridium complexes containing oxinato ligands
Published Date
Aug 1, 2009
Volume
12
Issue
8
Pages
806 - 807
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