Structural variation, dynamics, and catalytic application of palladium(ii ) complexes of di-N-heterocyclic carbene–amine ligands
Abstract
A series of palladium(II) complexes incorporating di-NHC-amine ligands has been prepared and their structural, dynamic and catalytic behaviour investigated. The complexes [trans-(kappa(2)-(tBu)CN(Bn)C(tBu))PdCl(2)] (12) and [trans-(kappa(2)-(Mes)CN(H)C(Mes))PdCl(2)] (13) do not exhibit interaction between the amine nitrogen and palladium atom respectively. NMR spectroscopy between -40 and 25 degrees C shows that the di-NHC-amine ligand is...
Paper Details
Title
Structural variation, dynamics, and catalytic application of palladium(ii ) complexes of di-N-heterocyclic carbene–amine ligands
Published Date
Jan 1, 2007
Journal
Issue
28
Pages
3065 - 3073
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