Enhanced nucleophilic fluorination and radiofluorination of organosilanes appended with potassium-chelating leaving groups
Abstract
Here we aimed to explore the feasibility of enhancing the fluorination of organosilanes by appending potassium-chelating groups to the substrates. For this purpose, eight organosilanes were prepared in which a linear or cyclic leaving group, with putative potassium-chelating ability, was attached covalently to a congested silicon atom via an ether linkage to serve as a potential nucleophilic assisting leaving group (NALG). Organosilicon-NALGs...
Paper Details
Title
Enhanced nucleophilic fluorination and radiofluorination of organosilanes appended with potassium-chelating leaving groups
Published Date
Feb 1, 2014
Volume
158
Pages
48 - 52
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