Match!

Butyltin(IV) citrates and tartrates: Structural characterization and their interaction with nucleotides

Published on Apr 1, 2013in Journal of Organometallic Chemistry2.07
· DOI :10.1016/j.jorganchem.2013.01.015
Hanna Pruchnik11
Estimated H-index: 11
(Wroclaw University of Environmental and Life Sciences),
Florian P. Pruchnik19
Estimated H-index: 19
(UWr: University of Wrocław)
Abstract
Abstract Butyltin complexes with biologically important hydroxyacids, citric HOOCCH 2 C(OH)(COOH)CH 2 COOH (C 6 H 8 O 7 ) acid and (2 R ,3 R )-(+)-tartaric HOOCCH(OH)CH(OH)COOH (C 4 H 6 O 6 ) acid: [Sn(C 4 H 9 ) 2 (C 6 H 6 O 7 )] ( 1 ), [Sn(C 4 H 9 ) 3 (C 6 H 7 O 7 )] ( 2 ), (phenH) 2 [Sn(C 4 H 9 ) 3 (C 6 H 5 O 7 )] ( 3 ), [Sn(C 4 H 9 ) 2 (C 4 H 4 O 6 )] ( 4 ), [Sn(C 4 H 9 ) 3 (C 4 H 5 O 6 )] ( 5 ), (phenH)[Sn(C 4 H 9 ) 3 (C 4 H 4 O 6 )] ( 6 ) and [{Sn(C 4 H 9 ) 3 } 2 (C 4 H 4 O 6 )] ( 7 ) have been synthesized and characterized by ESI–MS, IR and 1 H, 13 C and 119 Sn NMR spectra. Their structures and properties in solid state and solutions were proposed on the basis of the spectroscopic data and density functional theory (DFT) calculations at B3LYP/3-21G** level. Complexes in solutions in polar solvents are five-coordinate as evidenced by 13 C and 119 Sn NMR spectra. Geometries of the five-coordinate complexes were optimized with B3LYP/3-21G** calculations. The 13 C, 31 P and 119 Sn NMR spectra prove that complexes effectively interact with AMP, ATP and DAMP nucleotides forming Sn–OP bonds and N⋯H–O (nucleotide–carboxylate ligand) hydrogen bonds. In the case of dibutyltin complexes ( 1 and 4 ) nucleotides may also be coordinated as a chelating ligands via phosphate group and N7 atom of adenine residue.
  • References (42)
  • Citations (6)
References42
Newest
#1Hanna Pruchnik (Wroclaw University of Environmental and Life Sciences)H-Index: 11
#2Małgorzata Latocha (Medical University of Silesia)H-Index: 11
Last.Florian P. Pruchnik (UWr: University of Wrocław)H-Index: 19
view all 5 authors...
10 CitationsSource
#1Hanna Pruchnik (Wroclaw University of Environmental and Life Sciences)H-Index: 11
#2Tadeusz Lis (UWr: University of Wrocław)H-Index: 31
Last.Florian P. Pruchnik (UWr: University of Wrocław)H-Index: 19
view all 7 authors...
18 CitationsSource
#1Lourdes Rocamora-Reverte (Universidad Miguel Hernández de Elche)H-Index: 8
#2Estefanía Carrasco-García (Universidad Miguel Hernández de Elche)H-Index: 10
Last.Santiago Gómez-Ruiz (URJC: King Juan Carlos University)H-Index: 25
view all 7 authors...
26 CitationsSource
17 CitationsSource
#1Mario Waser (Johannes Kepler University of Linz)H-Index: 18
#2Katharina Gratzer (Johannes Kepler University of Linz)H-Index: 5
Last.Norbert Müller (Johannes Kepler University of Linz)H-Index: 33
view all 4 authors...
33 CitationsSource
#1Vaso Dokorou (UoI: University of Ioannina)H-Index: 10
#2Alexandra Primikiri (UoI: University of Ioannina)H-Index: 4
Last.Dimitra Kovala-Demertzi (UoI: University of Ioannina)H-Index: 37
view all 3 authors...
37 CitationsSource
#1Tushar S. Basu Baul (NEHU: North Eastern Hill University)H-Index: 23
#2Anup Paul (NEHU: North Eastern Hill University)H-Index: 15
Last.Ulli Englert (RWTH Aachen University)H-Index: 34
view all 11 authors...
24 CitationsSource
#1Regina de Carvalho Oliveira (Federal Fluminense University)H-Index: 1
#2Ricardo Erthal Santelli (Federal Fluminense University)H-Index: 29
107 CitationsSource
#1Malgorzata Gajewska (IST: Instituto Superior Técnico)H-Index: 2
#2Konstantin V. Luzyanin (IST: Instituto Superior Técnico)H-Index: 23
Last.Armando J. L. Pombeiro (IST: Instituto Superior Técnico)H-Index: 59
view all 6 authors...
17 CitationsSource
#1Sotiris K. Hadjikakou (UoI: University of Ioannina)H-Index: 35
#2Nick Hadjiliadis (UoI: University of Ioannina)H-Index: 36
278 CitationsSource
Cited By6
Newest
#1I. I. Seifullina (ODESSA)H-Index: 6
#2E. E. Martsinko (ODESSA)H-Index: 6
Last.Svitlana V. Shishkina (University of Kharkiv)H-Index: 5
view all 6 authors...
Source
#1Hanna Pruchnik (Wroclaw University of Environmental and Life Sciences)H-Index: 11
#2Teresa Kral (Wroclaw University of Environmental and Life Sciences)H-Index: 9
Last.Martin HofH-Index: 33
view all 3 authors...
2 CitationsSource
#1Hanna Pruchnik (Wroclaw University of Environmental and Life Sciences)H-Index: 11
5 CitationsSource
#1Iosr journalsH-Index: 1
#2E. N. IornumbeH-Index: 1
Last.T. A. Tor-AnyiinH-Index: 1
view all 5 authors...
1 CitationsSource
#1Hanna Pruchnik (Wroclaw University of Environmental and Life Sciences)H-Index: 11
#2Teresa Kral (Wroclaw University of Environmental and Life Sciences)H-Index: 9
Last.Martin HofH-Index: 33
view all 3 authors...
5 CitationsSource
#1Fang-Lin Li (Shihezi University)
#2Qi Chen (NKU: Nankai University)
Last.Liang-Fu Tang (NKU: Nankai University)H-Index: 14
view all 5 authors...
Source
View next paperSynthesis, structure, and magnetic properties of (6-9)-nuclear Ni(II) trimethylacetates and their heterospin complexes with nitroxides.