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Organometallic Compounds. XXIV. () Determination of all the possible isomerization reactions of coordination complexes by the use of permutations

Published on Sep 2, 2010in Bulletin des Sociétés Chimiques Belges
· DOI :10.1002/bscb.19700791111
Marcel Gielen25
Estimated H-index: 25
(ULB: Université libre de Bruxelles),
Noel Vanlautem1
Estimated H-index: 1
(ULB: Université libre de Bruxelles)
Abstract
Permutations may be used to describe the transformations of a given complex MLn into one of the n!/hr, possible isomers. The determination of the n! possible permutations gives all the isomerization paths of this complex occuring by nonbond‐rupture mechanisms. This is applied to the case of four; five‐ and six‐ coordinate structures and might be applied as well to higher coordination numbers. Copyright © 1970 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
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