Original paper
Steric Aspects of the Binding of Monofunctional Platinum(II) Complexes to Sites on Nucleobases: Metal Complex “Flatness” as a Structural Element of Speciation
Abstract
Through the use of an established repulsive energy methodology, the endocyclic nitrogens of the common nucleobases have been probed by monofunctional PtII(A)3 moieties, where A ≡ NH3 and (A)3 ≡ diethylenetriamine (dien) and N1,N1,N4,N7,N7-pentamethyldiene (pmdien). These three complexes have been selected to represent, respectively, a gradual buildup of bulk on either side of the coordination plane. The values of the resulting steric parameters,...
Paper Details
Title
Steric Aspects of the Binding of Monofunctional Platinum(II) Complexes to Sites on Nucleobases: Metal Complex “Flatness” as a Structural Element of Speciation
Published Date
Nov 1, 1998
Journal
Volume
37
Issue
24
Pages
6269 - 6275
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Notes
History