Probing hydrogen bonding to quinone anion radicals by 1H and 2H ENDOR spectroscopy at 35 GHz

Volume: 294, Issue: 3, Pages: 401 - 413
Published: Nov 1, 2003
Abstract
ENDOR spectroscopy at 35 GHz and 80 K was used to study the radical anion of 1,4-benzoquinone (BQ) in water and various alcohols. BQ̄-d4 in H2O and BQ̄-h4 in D2O were investigated with the aim to obtain information on the hydrogen bonds between the quinone oxygen and the respective solvent. The observed spectra were analyzed using the GENDOR program for the simulation of orientationally selected powder ENDOR spectra. From the spectral...
Paper Details
Title
Probing hydrogen bonding to quinone anion radicals by 1H and 2H ENDOR spectroscopy at 35 GHz
Published Date
Nov 1, 2003
Volume
294
Issue
3
Pages
401 - 413
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