Original paper
Structure, bonding, electronic and energy aspects of a new family of early lanthanide (La, Ce and Nd) complexes with phosphoric triamides: Insights from experimental and DFT studies
Abstract
A new family of isostructural early lanthanide(III) complexes (LnXPA) of the general formula Ln(XPA)2Cl3(solv)2, where Ln = La, Ce and Nd, XPA = (4-X-C6H4NH)P(O)(NC4H8O)2, X = H, F, Cl and Br, and solv = H2O and CH3OH, is introduced. X-ray crystallography shows that the replacement of the coordinated water by a methanol molecule may reduce the symmetry level of the unit cell from the orthorhombic crystal system and the space groupFdd2 to...
Paper Details
Title
Structure, bonding, electronic and energy aspects of a new family of early lanthanide (La, Ce and Nd) complexes with phosphoric triamides: Insights from experimental and DFT studies
Published Date
Jan 1, 2012
Journal
Volume
41
Issue
5
Pages
1597 - 1608
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Notes
History