Structure of the O-polysaccharide of Azorhizobium caulinodans HAMBI 216; identification of 3-C-methyl-d-rhamnose as a component of bacterial polysaccharides
Abstract
The O-polysaccharide was obtained from the lipopolysaccharide of the stem-nodulating nitrogen-fixing bacterium Azorhizobium caulinodans HAMBI 216 and studied by sugar and methylation analyses along with 1H and 13C NMR spectroscopy. The polysaccharide was found to have a linear pentasaccharide repeating unit containing d-rhamnose and its rarely occurring 2-O-methyl (Rha2OMe) and 3-C-methyl (Rha3CMe) derivatives and having the following structure:...
Paper Details
Title
Structure of the O-polysaccharide of Azorhizobium caulinodans HAMBI 216; identification of 3-C-methyl-d-rhamnose as a component of bacterial polysaccharides
Published Date
Sep 1, 2012
Journal
Volume
358
Pages
106 - 109
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