A general method for the synthesis of clerodane diterpenoids. Stereospecific total syntheses of (±)-15, 16-epoxy--cleroda-3, 13(16), 14-triene and (±)-maingayic acid

Volume: 44, Issue: 21, Pages: 6607 - 6622
Published: Jan 1, 1988
Abstract
null null A general method for the syntheses of null null null cis null null - and null null null trans null null -clerodane diterpenoids has been developed and its applications to the total syntheses of both representatives 11 and maingayic acid (32) in racemic forms are described. The common Δ4-3-octalone intermediates 2a and 2b were prepared from 3,4-dimethyl-2-cyclohexenone by a stereospecific conjugate addition-alkylation sequence and the...
Paper Details
Title
A general method for the synthesis of clerodane diterpenoids. Stereospecific total syntheses of (±)-15, 16-epoxy--cleroda-3, 13(16), 14-triene and (±)-maingayic acid
Published Date
Jan 1, 1988
Volume
44
Issue
21
Pages
6607 - 6622
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