Synthesis, structure, spectroscopic properties and biological activity of mixed diorganotin(IV) complexes containing pyridine-2-carbaldehyde thiosemicarbazonato and diphenyldithiophosphinato ligands.

Volume: 76, Issue: 3, Pages: 277 - 284
Published: Sep 15, 1999
Abstract
null null Reaction of the title ligands (HPyTSC and HS(S)PPh2, respectively) with R2SnO (R=Me, Et, Bu) in ethanol (EtOH) afforded the complexes [SnMe2(PyTSC)(S2PPh2)]·EtOH (1) and [SnR2(PyTSC)(S2PPh2)] (R=Et (2), Bu (3)). The structures of 1 and 2 were determined by single-crystal X-ray diffractometry. In both these complexes the tin atom is coordinated to an N,N,S-dentate thiosemicarbazonate ligand, an anisobidentate dithiophosphinato ligand...
Paper Details
Title
Synthesis, structure, spectroscopic properties and biological activity of mixed diorganotin(IV) complexes containing pyridine-2-carbaldehyde thiosemicarbazonato and diphenyldithiophosphinato ligands.
Published Date
Sep 15, 1999
Volume
76
Issue
3
Pages
277 - 284
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