Asymmetric Hydrogenation of 3,4-Hexanedione over PtSn Catalysts
Abstract
In this work, some results of the liquid-phase racemic and enantioselective hydrogenation of 3,4-hex- anedione are presented. The catalysts employed were platinum-based, supported on SiO2. Monometallic catalysts were modified with organotin precursors either chiral (hexa(-)-menthylditin, Men3Sn-SnMen3) or achiral (tetr- abutyltin, SnBu4), and they were obtained via surface organometallic chemistry on metals techniques. Asym- metric system was...
Paper Details
Title
Asymmetric Hydrogenation of 3,4-Hexanedione over PtSn Catalysts
Published Date
May 22, 2010
Journal
Volume
138
Issue
1-2
Pages
34 - 39
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