From Homogeneous to Heterogeneous Nucleation of Chain Molecules under Nanoscopic Cylindrical Confinement
Abstract
The crystallization of monodisperse linear polyethylene confined in nanoporous alumina is investigated with the calorimetric measurements. We observe a drastic change in crystallization behavior, specifically nucleation, with a decrease in the pore diameter. Crystallization in relatively larger pores with the diameters of 62 and 110 nm occurs at lower temperatures within a very narrow range, whereas crystallization in smaller pores with...
Paper Details
Title
From Homogeneous to Heterogeneous Nucleation of Chain Molecules under Nanoscopic Cylindrical Confinement
Published Date
Mar 28, 2007
Journal
Volume
98
Issue
13
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Notes
History