Original paper
Organostannanes Derived from (−)-Menthol: Controlling Stereochemistry during the Preparation of (1R,2S,5R)-Menthyldiphenyltin Hydride and Bis((1R,2S,5R)-menthyl)phenyltin Hydride
Abstract
Reaction of (1R,2S,5R)-menthylmagnesium chloride (MenMgCl) with triphenyltin chloride in THF proceeds with epimerization of the C-1 carbon of the menthyl group and results in a mixture of (1R,2S,5R)-menthyltriphenyltin (1) and (1S,2S,5R)-menthyltriphenyltin (2). Addition of Lewis bases such as triphenylphosphine to the THF solution of triphenyltin chloride prior to addition of the Grignard reagent suppresses epimerization and enables isolation...
Paper Details
Title
Organostannanes Derived from (−)-Menthol: Controlling Stereochemistry during the Preparation of (1R,2S,5R)-Menthyldiphenyltin Hydride and Bis((1R,2S,5R)-menthyl)phenyltin Hydride
Published Date
Jul 21, 1999
Journal
Volume
18
Issue
17
Pages
3342 - 3347
Citation AnalysisPro
You’ll need to upgrade your plan to Pro
Looking to understand the true influence of a researcher’s work across journals & affiliations?
- Scinapse’s Top 10 Citation Journals & Affiliations graph reveals the quality and authenticity of citations received by a paper.
- Discover whether citations have been inflated due to self-citations, or if citations include institutional bias.
Notes
History