Original paper

Ambient Temperature Sn-C Bond Cleavage Reaction Involving the Sn-n-butyl Group. Weak F···F Interactions in the Solid State Structure of [{nBu2SnO2C-C6H4-4-CF3}2O]2

Volume: 640, Issue: 6, Pages: 1147 - 1151
Published: Feb 12, 2014
Abstract
The reaction of bis(tri-n-butyltin)oxide, [nBu3Sn]2O, with HO2C–C6H4–4-CF3 (RfTol-CO2H) affords a coordination polymer [nBu3SnO2C–RfTol]n (1). 1 undergoes hydrolysis in the presence of atmospheric moisture, at room temperature, resulting in the formation of the diorgano stannoxane [{nBu2SnO2C–RfTol}2O]2 (2). The transformation of 1 to 2 is accompanied by a Sn–C bond cleavage reaction. Formation of 2 also occurs in a direct reaction, involving...
Paper Details
Title
Ambient Temperature Sn-C Bond Cleavage Reaction Involving the Sn-n-butyl Group. Weak F···F Interactions in the Solid State Structure of [{nBu2SnO2C-C6H4-4-CF3}2O]2
Published Date
Feb 12, 2014
Volume
640
Issue
6
Pages
1147 - 1151
Citation AnalysisPro
  • Scinapse’s Top 10 Citation Journals & Affiliations graph reveals the quality and authenticity of citations received by a paper.
  • Discover whether citations have been inflated due to self-citations, or if citations include institutional bias.