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Inorganic Chemistry Communications
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#1Xiaofei ZhuH-Index: 5
#2Haitao HanH-Index: 5
Last.Wuping LiaoH-Index: 25
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#1J. Mukiza (NUR: National University of Rwanda)
#2Gratien Habarurema (College of Science and Technology)H-Index: 1
Last.Richard BetzH-Index: 6
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Abstract The reaction of dithizone (H2dtz) with an organometallic rhenium(I) precursor; [Re(CO)5Cl] in ethanol led to the isolation of the octahedral organometallic fac-[Re(CO)3]+ core complex fac-[Re(CO)3(Hdtz)(dttz)] (1). The chelating ligand 1,2-diphenyltetrazolethione-5 zwitterion (dttz) in 1 was formed from the double deprotonation and cyclisation of dithizone in ethanol. The cyclisation of H2dtz to dttz zwitterion is a good example of the conversion of N,S-donor dithizone to S-donor ligand...
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Abstract In this study, the effects of four kinds of binders including polyimide (PI), sodium alginate (SA), polyvinylidene fluoride (PVDF), and sodium carboxymethyl cellulose (CMC) on the electrochemical properties of a high capacity silicon composite anode (SMG@C) were investigated. Phase constitutes and morphologies of the SMG@C anode materials were carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The electrochemical pr...
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#2Shuai Huang (Qingdao University)
Last.Mengmeng Shang (Qingdao University)
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Abstract Red-emitting phosphors have attracted considerable interest for their applications in warm white light-emitting diodes (LEDs). A series of novel red emitting Eu3+-doped Ba2GdVO6 phosphors were prepared by a solid-state reaction annealed at 1300 oC for 6 h. Under the excitation of blue light (465 nm), Ba2GdVO6:Eu3+ phosphors emit pure red light. The critical distance at which concentration occurs is determined to be 8.7 A when the doping concentration reached up to 20mol%. More important...
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#1Rosita DianaH-Index: 13
#2Barbara PanunziH-Index: 17
Last.Ugo CarusoH-Index: 18
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Abstract Three zinc (II) complexes were synthesized from O,N,O-tridentate ligands with a charged side chain and a different electron withdrawing substituent. Metallated polymers with emission color tuning based on the same ligands moved interest. In the present study we collected information on the coordination environment and on the photoluminescence performance of the related model complexes. In pyridine solution RGB (red-green-blue) emission was achieved by lowering the withdrawing strength o...
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#1Ganna A. Senchyk (KNU: Taras Shevchenko National University of Kyiv)H-Index: 11
#2Andrey B. Lysenko (KNU: Taras Shevchenko National University of Kyiv)H-Index: 9
Last.Kostiantyn V. Domasevitch (KNU: Taras Shevchenko National University of Kyiv)H-Index: 2
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Abstract A new heterofunctional ligand (Me2trGly-H = 3,5-dimethyl-(1,2,4-triazol-4-yl)-acetic acid), was employed for the synthesis of two coordination polymers [Ag4(Me2trGly-H)2.25(Me2trGly)1.75(NO3)2](NO3)0.25⋅6H2O (1) and [Ag4(UO2)(H2O)(Me2trGly)4(NO3)2]⋅5H2O (2). In compound 1, the triazole functional groups interact with Ag+ forming the stable tetranuclear rhombic {Ag4(Me2tr)4} motif, while the partially deprotonated carboxylic functions are left uncoordinated. NO3¯ anions are located betwe...
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#1Ce Liu (Liaoning University)
#2Zhiqiang Xing (Liaoning University)
Last.Zheng-Bo Han (Liaoning University)H-Index: 21
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Abstract A micron sized Zn (II) coordination polymer (CP), namely {[Zn(L)(5-mip)]·EtOH}(1) (L =1,3-bis(benzimidazol-1-yl)-2-propanol and 5-H2mip = 5-methyisophthalic acid), was synthesized by ultrasonic irradiation at room temperature. The effects of ultrasonic power and time on the morphology and size of 1 were investigated in detail. Interestingly, micron sized 1 with considerable stability is can be used as an excellent and reused heterogeneous catalyst for carbon dioxide cycloaddition to epo...
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Abstract A novel functional material, Zinc (II) tetra-[α-(p-amino)benzyloxyl]phthalocyanine (ZnPc) upon covalent integration with glycidoxypropyltrimethoxy silane modified TiO2 (GPTMS/TiO2) is prepared here for the first time in order to improve the visible photocatalytic activity of TiO2. The photocatalytic property of obtained ZnPc-GPTMS/TiO2 hybrid was investigated by carrying out the photodegradation of di-anionic azo dye Acid Black 1 (AB1) in aqueous solution under visible light irradiation...
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#1Yan Liu (BIT: Beijing Institute of Technology)
#2Zhong Zhang (BIT: Beijing Institute of Technology)H-Index: 4
Last.Guo-Yu Yang (BIT: Beijing Institute of Technology)H-Index: 7
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Abstract A new Ni11-cluster sandwiched phosphotungstate supported by Ni(H2O)5 group H2[Ni(H2O)6]{[Ni11(OH)6(H2O)(en)2(Hen)2(L)3](PW9O34)2[Ni- (H2O)5]}·20H2O (1, en = 1,2-ethylenediamine, L = iminodiacetate), has been made under hydrothermal conditions and characterized by IR spectrum, thermogravimetric analysis, elemental analysis, single-crystal X-ray diffraction and powder X-ray diffraction, respectively. The structure analysis reveals that 1 contains the Ni11-cluster sandwiched polyoxoanion {...
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#2Jiasen Zhu (SYSU: Sun Yat-sen University)
Last.Jian Chen (SYSU: Sun Yat-sen University)H-Index: 65
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Abstract Herein, the oxygen evolution reaction (OER) catalytic activity of FeNi3N is significantly improved through the incorporation of FeNi3 as a result of the controllable composition of the Fe source. The as-prepared FeNi3N/FeNi3 achieves overpotential of 254 mV at a current density of 10 mA cm-2, which is superior to those of pristine FeNi3N, owing to the synergistic effect between FeNi3N and FeNi3.
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