Chemical Communications
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#1Robert Mundil (university of lille)
#2Franck Kayser (university of lille)
Last. Philippe Zinck (university of lille)H-Index: 22
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Organocatalysis has provided new tools for making block copolymers, in particular active species able to polymerize monomers of different chemical nature such as cyclic esters, cyclic carbonates and epoxides. We report herein the first example of an organocatalytic active species able to polymerize sequentially a cyclic ester, e-decalactone, and a vinyl monomer, methyl methacrylate. The resulting block copolymer shows the properties of thermoplastic elastomers.
#1Alexander KrylovH-Index: 16
#2Irena SenkovskaH-Index: 45
Last. Stefan KaskelH-Index: 81
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Experimental in situ observations of phase coexistence in switchable metal-organic frameworks are reported to provide a fundamental understanding of dynamic adsorbents that can change their pore structure in response to external stimuli. A prototypical flexible pillared layer framework DUT-8(Ni) (DUT = Dresden University of Technology) was studied under hydrostatic pressure by in situ Raman spectroscopy on single crystals. The closing transition of the open pore phase (op) containing DMF in the ...
#1Bizhe SuH-Index: 5
#2Hanqin LiangH-Index: 11
Last. Denis Y. W. YuH-Index: 26
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A sodium-rich vanadium compound, Na4V2O7, is investigated as a cathode material for sodium-ion batteries, with a high reversible capacity of 194 mAh g-1 after activating to 4.7 V. By limiting the cut-off voltage to 4.4 V, a good capacity retention of 93% after 50 cycles is achieved. The material exhibits negligible volume variation of 1.04% during Na+ (de-)intercalation, demonstrating that Na4V2O7 is structurally-stable.
#1Wen‐Tse HuangH-Index: 1
#2Suk-Young Yoon (Hongik University)H-Index: 1
Last. Ru-Shi LiuH-Index: 66
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The broadband near-infrared CuInS2/ZnS quantum dot up to 94.8% quantum yield was synthesized with fast precursor decomposition leading to monomer conversion improvement. In the mini-LED package, the device showed high power efficiency and stability also demonstrated with penetration test and vein imaging showing its potential biomedical application to theranostics field.
#1Abbie Leggott (University of Leeds)
#2Justin E. Clarke (University of Leeds)H-Index: 2
Last. Adam Nelson (University of Leeds)H-Index: 29
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The feasibility of using activity-directed synthesis to drive antibacterial discovery was investigated. An array of 220 Pd-catalysed microscale reactions was executed, and the crude product mixtures were evaluated for activity against Staphylococcus aureus. Scale-up of the hit reactions, purification and evaluation, enabled expansion of a class of antibacterial quinazolinones. The novel antibacterials had MICs from 0.016 μg mL−1 (i.e. 38 nM) to 2–4 μg mL−1 against S. aureus ATCC29213.
#1Guanghui Wang (University of Marburg)
#2Zijun Zhou (University of Marburg)H-Index: 2
Last. Eric Meggers (University of Marburg)H-Index: 51
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The first example of a chiral osmium catalyst is reported in which the overall chirality originates exclusively from a stereogenic metal center (metal-centered chirality) with all coordinating ligands being achiral. The non-C2-symmetric chiral-at-metal complex contains two cyclometalated 7-methyl-1,7-phenanthrolinium heterocycles which can be described as two chelating pyridylidene remote N-heterocyclic carbene (rNHC) ligands. The octahedral coordination sphere is completed with one CO and one a...
#1Congcong ChenH-Index: 4
#2Shuaishuai WangH-Index: 5
Last. Hongzhi CaoH-Index: 24
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A facile enzymatic modular assembly strategy for the preparative-scale synthesis of poly-N-acetyllactosamine (poly-LacNAc) glycans with varied lengths and designed sialylation and/or fucosylation patterns is described. These glycans were printed as a microarray to investigate their interactions with a panel of glycan binding proteins (GBPs). Binding affinities revealed that the avidity of GBPs could be largely affected by the length and the patterns of sialylation and fucosylation.
#1Shouyi YuanH-Index: 7
#2Junwei Lucas BaoH-Index: 13
Last. Yongyao XiaH-Index: 73
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We propose a carbonate-based electrolyte optimized with dual cations and ionic liquid for high-efficiency Li metal batteries with high-voltage cathode. An average coulombic efficiency of Li deposition of 99.6% is achieved due to the salt-rich solid electrolyte interphase and Na guided uniform Li plating. The Li||NCM811 cells can be cycled with limited Li (N/P=1) over 90 cycles. Additional advantage is that it improves the thermal stability of the NCM811 cathode.
In an effort to rationally design economic electrocatalysts, zinc-substituted cobalt phosphate and pyrophosphate were prepared by facile template-free combustion synthesis. They act as efficient stable bifunctional electrocatalysts owing to the tuning of oxygen affinity by zinc substitution and catalytically active cobalt sites. Exploiting their bifunctional activity, these cobalt (pyro)phosphates were incorporated into zinc-air battery in alkaline electrolyte.
#1Sachio Suzuki (Nagoya Institute of Technology)
#2Masahiro Ikuta (Nagoya Institute of Technology)
Last. Shinya Tsukiji (Nagoya Institute of Technology)H-Index: 24
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The development of methods that allow detection of ligand–target engagement in cells is an important challenge in chemical biology and drug discovery. Here, we present a Golgi recruitment (G-REC) assay in which the ligand binding to the target protein can be visualized as Golgi-localized fluorescence signals. We show that the G-REC assay is applicable to the detection of various ligand–target interactions, ligand affinity comparison among distinct protein isoforms, and the monitoring of unmodifi...
Top fields of study
Organic chemistry
Inorganic chemistry