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Dulali Biswas
2Publications
2H-index
170Citations
Publications 2
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The complex [Et4N]2[WVIO2(mnt)2] (1), [Et4N]2[WIVO(mnt)2] (2), and [Et4N]2[WVIO(S2)(mnt)2] (3) (mnt2- = 1,2-dicyanoethylenedithiolate) have been synthesized as possible models for the tungsten cofactor of inactive red tungsten protein (RTP) and the active aldehyde ferredoxin oxidoreductase (AOR) of the hyperthermophilic archaeon Pyrococcus furiosus. The [Ph4P]+ salt of the complex anion of 1·2H2O crystallizes in space group Pbcn, with a = 20.526(3) A, b = 15.791(3) A, c = 17.641(3) A, and Z = 4....
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