Match!
Jacob C. Lutter
University of Michigan
Inorganic chemistryChemistryLanthanideMetallacrownCoordination complex
9Publications
3H-index
59Citations
What is this?
Publications 10
Newest
#1Jacob C. LutterH-Index: 3
Last. Vincent L. Pecoraro (UM: University of Michigan)H-Index: 68
view all 11 authors...
Multimodal probes capable of combining imaging modalities within a single molecule are in high demand today as they can provide information at both molecular and anatomical levels. Herein, a study was conducted on a series of gallium(III)/lanthanide(III) bis(12-MC-4) metallacrowns (MCs) with the general composition {Ln[12-MCGa (III) N(shi) -4]}2 (iph)4 (Ln-Ix , x=0, 4, 8, 12), where shi and iph are salicylhydroximate and isophthalate ligands, respectively, or their iodinated derivatives. For Yb-...
1 CitationsSource
#1Jacob C. Lutter (UM: University of Michigan)H-Index: 3
#2Beatriz A. Lopez Bermudez (UM: University of Michigan)H-Index: 1
Last. Vincent L. Pecoraro (UM: University of Michigan)H-Index: 68
view all 5 authors...
Abstract The synthesis and characterization of {Ln[12-MCGaIIIN(eshi)-4]}2(iph)4 and {Ln[12-MCGaIIIN(shi)-4]}2(miph)4 metallacrowns (MCs), where shi3− is salicylhydroximate, eshi3− is 4-ethynylsalicylhydroximate, iph2− is isopthalate, and miph2− is 5-maleimidoisophthalate, is reported. The ethynyl functionality allows for coupling of MCs to azides using copper(I) catalyzed alkyne-azide cycloaddition (CuAAC), while the maleimido functionality allows for coupling of the MCs to thiol-bearing compoun...
1 CitationsSource
#1Jacob C. Lutter (UM: University of Michigan)H-Index: 3
#2Lillian V. A. Hale (UM: University of Michigan)H-Index: 5
Last. Ginger V. Shultz (UM: University of Michigan)H-Index: 7
view all 3 authors...
Graduate students play a critical role in undergraduate education at doctoral-granting institutions and yet their training is often brief and overgeneralized. Little is known about how they develop knowledge for teaching chemistry in this context. To further understand how graduate students develop knowledge for teaching, we used a questionnaire to measure pedagogical content knowledge of solution chemistry concepts. These concepts are revisited frequently in the undergraduate curriculum, partic...
Source
#1Jacob C. Lutter (UM: University of Michigan)H-Index: 3
#2Svetlana V. Eliseeva (CNRS: Centre national de la recherche scientifique)H-Index: 30
Last. Vincent L. Pecoraro (UM: University of Michigan)H-Index: 68
view all 5 authors...
2 CitationsSource
#1Jacob C. Lutter (UM: University of Michigan)H-Index: 3
#2Curtis M. Zaleski (SU: Shippensburg University of Pennsylvania)H-Index: 17
Last. Vincent L. Pecoraro (UM: University of Michigan)H-Index: 68
view all 3 authors...
Abstract Metallacrown (MC) research grows each year, in particular with regard to applications of these molecules. This review will focus on the properties and applications of these compounds since 2014. In the solid state metallacrowns have been used as building blocks for one- and two-dimensional structures as well as metal–organic frameworks. In addition, MCs have been used as a single source precursor for metal oxides including incorporation into multiwalled carbon nanotubes. Recent solution...
2 CitationsSource
#1Thaddeus T. Boron (SRU: Slippery Rock University of Pennsylvania)H-Index: 8
#2Jacob C. Lutter (UM: University of Michigan)H-Index: 3
Last. Vincent L. PecoraroH-Index: 68
view all 10 authors...
A family of DyX4M(12-MCMnIII(N)shi-4) compounds were synthesized and magnetically characterized (X = salicylate, acetate, benzoate, trimethylacetate, M = NaI or KI). The bridging ligands were systematically varied while keeping the remainder of the MC-geometry constant. The type of monovalent cation, necessary for charge balance, was also altered. The dc magnetization and susceptibility of all compounds were similar across the series. Regardless of the identity of the countercation, the Dy(Hsal)...
15 CitationsSource
#1Lillian V. A. Hale (UM: University of Michigan)H-Index: 5
#2Jacob C. Lutter (UM: University of Michigan)H-Index: 3
Last. Ginger V. Shultz (UM: University of Michigan)H-Index: 7
view all 3 authors...
Graduate students play a critical role in undergraduate education at doctorate granting institutions; but generally have minimal opportunity to develop teaching expertise. Furthermore, little is known about how graduate students develop teaching expertise in this context. We investigated the development of topic-specific pedagogical content knowledge among chemistry graduate student teaching assistants (GTAs). Thin layer chromatography was selected as the topic of investigation because undergrad...
5 CitationsSource
#1Curtis M. Zaleski (SU: Shippensburg University of Pennsylvania)H-Index: 17
#2Jacob C. Lutter (SU: Shippensburg University of Pennsylvania)H-Index: 3
Last. Matthias Zeller (YSU: Youngstown State University)H-Index: 39
view all 3 authors...
Source
#1Michael R. Azar (SU: Shippensburg University of Pennsylvania)H-Index: 1
#2Thaddeus T. Boron (SRU: Slippery Rock University of Pennsylvania)H-Index: 8
Last. Curtis M. Zaleski (SU: Shippensburg University of Pennsylvania)H-Index: 17
view all 11 authors...
The inclusion of LnIII ions into the 12-MC-4 framework generates the first heterotrimetallic complexes of this molecular class. The controllable and deliberate preparations of these compounds are demonstrated through 12 crystal structures of the LnIIIMI(OAc)4[12-MCMnIII(N)shi-4](H2O)4·6DMF complex, where OAc– is acetate, shi3- is salicylhydroximate, and DMF is N,N-dimethylformamide. Compounds 1–12 have MI as NaI, and LnIII can be PrIII (1), NdIII (2), SmIII (3), EuIII (4), GdIII (5), TbIII (6), ...
33 CitationsSource
#1Jacob C. Lutter (SU: Shippensburg University of Pennsylvania)H-Index: 3
#2Jeff W. Kampf (UM: University of Michigan)H-Index: 52
Last. Curtis M. Zaleski (SU: Shippensburg University of Pennsylvania)H-Index: 17
view all 4 authors...
The title compound [Mn6(C7H4NO3)5(C3H5O2)2(C4H6N2)4.17(C3H7NO)1.83]·0.24C3H7NO·1.36CH3OH or Mn(II)(C3H5O2)2[15-MCMn(III)N(shi)-5](Me—Im)4.17(DMF)1.83·0.24DMF·1.36MeOH (where MC is metallacrown, shi3− is salicyl­hydroximate, Me—Im is 1-methyl­imidazole, DMF is N,N-di­methyl­formamide, and MeOH is methanol), contains an MnII ion in the central cavity and five MnIII ions in the MC ring. The central MnII ion is seven coordinate and has a geometry best described as distorted face-capped trigonal pris...
1 CitationsSource
1