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Marc Schmidtmann
University of Oldenburg
242Publications
36H-index
4,630Citations
Publications 242
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#1Jens BielefeldH-Index: 2
Last.Sven DoyeH-Index: 32
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The first examples of early-transition-metal-catalyzed hydroaminoalkylation reactions of allenes are reported. Initial studies performed with secondary aminoallenes led to the identification of a suitable titanium catalyst and revealed that under the reaction conditions, the initially formed hydroaminoalkylation products undergo an unexpected titanium-catalyzed rearrangement to form the thermodynamically more stable allylamines. The assumption that this rearrangement involves a reactive allylic ...
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